Superconducting Titanium Nitride in Through-Silicon Vias for 3D Integration of Qubits

Quantum computers based on superconducting qubits are advancing rapidly but face significant challenges in scaling to larger numbers of qubits while maintaining coherence and efficient addressing. Utilizing 3D integration with through-silicon vias (TSVs) presents a promising solution by enabling vertical signal routing and reducing interconnect crowding. This paper identifies Titanium Nitride (TiN) deposition via Metal-Organic Chemical Vapor Deposition (MOCVD) as an effective method for achieving conformal and superconductive coating of TSVs. A test structure is introduced to provide a rapid feedback loop for the development of this metallization. Additionally, a strategy is proposed to evaluate and interpret cryogenic resistance measurements showing transitions to superconductivity. This strategy is employed to identify the influence of deposition parameters on TiN coating on TSV sidewalls and to develop a comprehensive model explaining the deposition mechanism inside TSVs.