• English
  • Deutsch
  • Log In
    Password Login
    or
  • Research Outputs
  • Projects
  • Researchers
  • Institutes
  • Statistics
Repository logo
Fraunhofer-Gesellschaft
  1. Home
  2. Fraunhofer-Gesellschaft
  3. Artikel
  4. Structure, stability and permeation properties of NaA zeolite membranes for H2O/H2 and CH3OH/H2 separations
 
  • Details
  • Full
Options
2018
Journal Article
Titel

Structure, stability and permeation properties of NaA zeolite membranes for H2O/H2 and CH3OH/H2 separations

Abstract
NaA zeolite membranes were synthesised in the secondary growth hydrothermal method based on the seeding of the inner surface of a ceramic a-alumina tube. The impacts of crystallisation time and zeolite precursor concentration (in H2O) were investigated. The structure and stability of the prepared NaA zeolite membranes were also investigated with operating temperatures, times and pressures. The results indicate that the optimal synthesis gel molar composition was 3Na2O: 2SiO2: Al2O3: 200H2O. This led to cubic-shaped NaA zeolite which showed good stability. The optimal NaA zeolite membrane had H2O and CH3OH fluxes of 2.77 and 0.19 kg/m2h, with H2O/H2 and CH3OH/H2 separation factors of IF and 0.09 at a temperature of 30 °C. The NaA zeolite membrane had high thermal stability, but poor separation performance at high temperature (240 °C). The results suggested that the H2 permeation flux is significantly influenced by preferential adsorption of vapour in the NaA zeolite membrane.
Author(s)
Moon Lee, S.
Xu, N.
Grace, John R.
Li, A.
Lim, C.J.
Kim, S.S.
Fotovat, F.
Schaadt, Achim
White, Robin J.
Zeitschrift
Journal of the European Ceramic Society
Thumbnail Image
DOI
10.1016/j.jeurceramsoc.2017.08.012
Language
English
google-scholar
Fraunhofer-Institut für Solare Energiesysteme ISE
Tags
  • Energietechnik

  • Wasserstofftechnologie

  • thermochemischer Prozess

  • zeolite

  • Membrane Structure

  • stability

  • separation factor

  • Sodalite

  • Cookie settings
  • Imprint
  • Privacy policy
  • Api
  • Send Feedback
© 2022