Evaluation of new organosolv dissolving pulps. Pt.II: Structure and NMMO processability of the pulps

The supermolecular structure of dissolving pulps produced from hardwood by the organosolv processes Acetosolv, Formacell, and Milox was characterized by physical methods (TEM, WAXS, SAXS, NMR) and compared with conventional Sulfite and standard commercial dissolving pulps. The suitability of the pulps for the NMMO technology was tested by spinning fibres and blowing films, whose structural and mechanical properties have also been determined. With TEM it was shown that the TCF-bleached organosolv pulps have only the primary (Formacell), the primary and S1 (Milox), or mainly the S1 (Acetosolv) layers exposed to the surface, whereas Sulfite pulping exposes the S2 cell wall layer. Especially for Milox and Acetosolv Eucalyptus wood pulps, a reduced degree of crystallinity was found, both with WAXS and NMR. The SAXS results indicate a lower pore intersection length for the new pulps as compared to conventional pulps. Unbleached organosolv pulps show a lower crystallinity, very low pore intersection lengths, and an average crystallite shape different from their bleached counterparts. The dissolution behaviour in NMMO and the processability of the bleached organosolv pulps was satisfactory so far. Fibres and films could be produced with structural and mechanical properties comparable with conventional Sulfite and standard commercial dissolving pulp products. However, unbleached organosolv pulps did not meet the requirements of the NMMO process.