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  4. A high-performance, durable and low-cost proton exchange membrane electrolyser with stainless steel components
 
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2022
Journal Article
Title

A high-performance, durable and low-cost proton exchange membrane electrolyser with stainless steel components

Abstract
Proton exchange membrane water electrolysis (PEMWE) is the most promising technology for sustainable hydrogen production. However, it has been too expensive to compete with current state-of-the-art technologies due to the high cost of titanium bipolar plates (BPPs) and porous transport layers (PTLs). Here, we report a high-performance, durable and low-cost PEMWE cell with coated stainless steel (ss) BPPs and PTLs. When using uncoated ss components in the PEMWE cell, the cell depolarizes rapidly, reaching 2 V at only 0.15 A cm-2. After the application of non-precious metal coatings of Ti and Nb/Ti on the ss-BPP and ss-PTL, respectively, the current density can be increased by a factor of 13 while maintaining the same performance. Extensive physical and electrochemical characterization supported by pore network modelling shows that the Nb/Ti coating on the ss-PTL leads to efficient water and gas transport at the interface with the anode. The PEMWE cell with coated ss components was evaluated in an accelerated stress test (AST) for more than 1000 h. No sign of Fe contamination in either the membrane or the electrodes is observed at the end of the test. With our results, we demonstrate that PEMWE cells can be manufactured almost entirely in ss, facilitating an unprecedented cost reduction in this technology and advancing the widespread use of green H2.
Author(s)
Stiber, Svenja
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Sata, Noriko
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Morawietz, Tobias
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Ansar, S.A.
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Jahnke, T.
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Lee, J. Kang
University of Toronto
Bazylak, Aimy
University of Toronto
Fallisch, Arne
Fraunhofer-Institut für Solare Energiesysteme ISE  
Gago, Aldo
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Friedrich, K. Andreas
Deutsches Zentrum für Luft- und Raumfahrt (DLR)
Journal
Energy & environmental science  
Project(s)
Novel modular stack design for high pressure PEM water electrolyzer technology with wide operation range and reduced cost  
Cost-effective PROton Exchange MEmbrane WaTer Electrolyser for Efficient and Sustainable Power-to-H2 Technology  
Funding(s)
H2020-EU.3.3.  
H2020-EU.2.1.3.  
Funder
European Commission  
European Commission  
Open Access
DOI
10.1039/d1ee02112e
10.24406/h-425299
File(s)
Stiber2022_A high-performance, durable and low-cost proton.pdf (5.78 MB)
Rights
CC BY 4.0: Creative Commons Attribution
Language
English
Fraunhofer-Institut für Solare Energiesysteme ISE  
Keyword(s)
  • coated bipolar plate

  • PEM water electrolysis

  • stainless steel components

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