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  4. GITT Analysis of Lithium Insertion Cathodes for Determining the Lithium Diffusion Coefficient at Low Temperature: Challenges and Pitfalls
 
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2020
Journal Article
Title

GITT Analysis of Lithium Insertion Cathodes for Determining the Lithium Diffusion Coefficient at Low Temperature: Challenges and Pitfalls

Abstract
Understanding the thermodynamic and kinetic properties of electrode materials for Li-ion batteries is of great importance for their knowledge-based optimization and development of novel materials and cell designs. The galvanostatic intermittent titration technique (GITT) is widely applied in battery research to study the state-of-charge (SOC) dependent kinetics of Li ion insertion in anode and cathode materials. While kinetic data at high and ambient temperatures are largely available, low temperature diffusion and rate coefficients are hardly reported in the literature and can vary by orders of magnitude for identical active materials. Herein, we demonstrate and discuss several challenges and pitfalls in the application and evaluation of GITT measurements for determining kinetic coefficients of Li-insertion electrodes, which become especially important at low temperature. This includes theoretical considerations and an experimental analysis of the promising cathode material LiNi0.5Co0.2Mn0.3O2 (NCM523) in the wide temperature range of -40 to 40 °C. We show how the choice of experimental conditions for the GITT measurements and of the subsequent mathematical evaluation procedure to determine the lithium diffusion coefficient significantly influence the derived value of the diffusion coefficient in NCM523. The results suggest that the large scattering of reported values of the diffusion coefficient could be caused by the use of different evaluation procedures. Simple calculation methods appear to be less suited the lower the temperature is. We outline that the proper estimation of the apparent Li ion chemical diffusion coefficient from GITT data requires an additional impedance analysis and a detailed knowledge of the cathode microstructure.
Author(s)
Nickol, Alexander  
Fraunhofer-Institut für Keramische Technologien und Systeme IKTS  
Schied, Thomas
TU Dresden
Heubner, Christian  
Fraunhofer-Institut für Keramische Technologien und Systeme IKTS  
Schneider, Michael  
Fraunhofer-Institut für Keramische Technologien und Systeme IKTS  
Michaelis, Alexander  orcid-logo
Fraunhofer-Institut für Keramische Technologien und Systeme IKTS  
Bobeth, Manfred
TU Dresden
Cuniberti, Gianaurelio
TU Dresden
Journal
Journal of the Electrochemical Society  
Project(s)
TT-Kin
TT-Kin
Funder
Sächsische Aufbaubank - Förderbank SAB  
Sächsische Aufbaubank - Förderbank SAB  
Open Access
DOI
10.1149/1945-7111/ab9404
Additional full text version
Landing Page
Language
English
Fraunhofer-Institut für Keramische Technologien und Systeme IKTS  
Keyword(s)
  • lithium ion battery

  • galvanostatic intermittent titration technique

  • NCM Cathode

  • charge transfer kinetics

  • lithium diffusion coefficient

  • Low-Temperature

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