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Resonance effects in Raman scattering from polycrystalline diamond films.

Resonanzeffekte in der Ramanstreuung von polykristallinen Diamantfilmen
 
: Koidl, P.; Wagner, J.; Wild, C.

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Applied Physics Letters 59 (1991), No.7, pp.779-781 : Abb.,Lit.
ISSN: 0003-6951
ISSN: 1077-3118
English
Journal Article
Fraunhofer IAF ()
CVD Diamant; CVD diamond; polycrystalline diamond; polykristalliner Diamant; raman scattering; Ramanstreuung

Abstract
We report on a Raman spectroscopic study of polycrystalline diamond films using a wide range of incident photon energies (1.16-4.82 eV). The scattering intensity of amorphous sp2-bonded carbon is found to vary considerably as a function of the incident photon energy as compared to the strength of the 1332 cm-1 Raman line from sp2-bonded diamond. There is also a frequency downshift of the apparent peak position for scattering from the sp2-bonded carbon with decreasing photon energy. Excitation in the infrared range is shown to give a high sensitivity to scattering from amorphous sp2-bonded carbon whereas ultraviolet excitation enhances the 1332 cm-1 signal from crystalline diamond considerably even in nanocrystalline films.

: http://publica.fraunhofer.de/documents/PX-31822.html