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Polyoxopalladate-Loaded Metal-Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis

: Bhattacharya, Saurav; Ayass, Wassim W.; Taffa, Dereje H.; Nisar, Talha; Balster, Torsten; Hartwig, Andreas; Wagner, Veit; Wark, Michael; Kortz, Ulrich


Inorganic Chemistry 59 (2020), No.15, pp.10512-10521
ISSN: 0020-1669
ISSN: 1520-510X
Journal Article
Fraunhofer IFAM ()
palladium; composites; metal organic frameworks; Catalysts; catalysis

We report on the synthesis and characterization of the first polyoxo-noble-metalate-containing metal-organic framework (MOF) material, wherein the preformed MIL-101 has been impregnated with the discrete, cuboid-shaped polyoxopalladate [Pd13Se8O32]6- (Pd13Se8), leading to the composite Pd13Se8@MIL-101. This material was characterized by FTIR, TGA, elemental analysis, powder-XRD, N2 sorption (BET), SEM-EDX, and XPS. Furthermore, the Pd13Se8@MIL-101 composite was shown to be an effective, stable, and recyclable heterogeneous precatalyst for the Suzuki-Miyaura cross-coupling reaction at room temperature utilizing environmentally benign solvents, such as water and methanol.