• English
  • Deutsch
  • Log In
    Password Login
    Research Outputs
    Fundings & Projects
    Researchers
    Institutes
    Statistics
Repository logo
Fraunhofer-Gesellschaft
  1. Home
  2. Fraunhofer-Gesellschaft
  3. Artikel
  4. Polyoxopalladate-Loaded Metal-Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis
 
  • Details
  • Full
Options
2020
Journal Article
Title

Polyoxopalladate-Loaded Metal-Organic Framework (POP@MOF): Synthesis and Heterogeneous Catalysis

Abstract
We report on the synthesis and characterization of the first polyoxo-noble-metalate-containing metal-organic framework (MOF) material, wherein the preformed MIL-101 has been impregnated with the discrete, cuboid-shaped polyoxopalladate [Pd13Se8O32]6- (Pd13Se8), leading to the composite Pd13Se8@MIL-101. This material was characterized by FTIR, TGA, elemental analysis, powder-XRD, N2 sorption (BET), SEM-EDX, and XPS. Furthermore, the Pd13Se8@MIL-101 composite was shown to be an effective, stable, and recyclable heterogeneous precatalyst for the Suzuki-Miyaura cross-coupling reaction at room temperature utilizing environmentally benign solvents, such as water and methanol.
Author(s)
Bhattacharya, Saurav
Department of Life Sciences and Chemistry, Jacobs University
Ayass, Wassim W.
Department of Life Sciences and Chemistry, Jacobs University
Taffa, Dereje H.
Institute of Chemistry, Carl von Ossietzky University Oldenburg
Nisar, Talha
Department of Physics and Earth Sciences, Jacobs University
Balster, Torsten
Department of Physics and Earth Sciences, Jacobs University
Hartwig, Andreas  
Fraunhofer-Institut für Fertigungstechnik und Angewandte Materialforschung IFAM  
Wagner, Veit
Department of Physics and Earth Sciences, Jacobs University
Wark, Michael
Institute of Chemistry, Carl von Ossietzky University Oldenburg
Kortz, Ulrich
Department of Life Sciences and Chemistry, Jacobs University
Journal
Inorganic Chemistry  
DOI
10.1021/acs.inorgchem.0c00875
Language
English
Fraunhofer-Institut für Fertigungstechnik und Angewandte Materialforschung IFAM  
Keyword(s)
  • palladium

  • composites

  • metal organic frameworks

  • Catalysts

  • catalysis

  • Cookie settings
  • Imprint
  • Privacy policy
  • Api
  • Contact
© 2024