Menke, K.K.MenkeBrehler, K.P.K.P.BrehlerBoehnlein Mauss, J.J.Boehnlein Mauss2022-03-082022-03-082000https://publica.fraunhofer.de/handle/publica/304539Composite solid propellant contains a crystalline inorganic oxidant, a binder with a liq. poly-OH-substd. prepolymer, crosslinking agent(s), polymer-specific plasticiser, antioxidant and adhesion promoter, a ferrocene deriv. coupled to the binder as burning modifier and opt. a metallic fuel and/or energy-rich nitramine. The ferrocene deriv. is a ferrocenyl methyl ether or ferrocenyl-carboxylate ester with free OH gps. of formula (I): Z = the ether gp. CH2-OX or the ester gp. C(O)-O-X; X = an oligoalkylene glycol or diol gp.; R = satd. hydrocarbyl or H. Also claimed is a method of producing the propellant. USE - Solid fuel of this type is esp. useful as rocket or gas generator fuel. ADVANTAGE - The ferrocene deriv., which has low viscosity and can be prepd. easily, is immobilised by chemical bonding of its OH gps. to the polymer during cure.de608660patent1995-19516528