Bhattacharya, SauravSauravBhattacharyaAyass, Wassim W.Wassim W.AyassTaffa, Dereje H.Dereje H.TaffaNisar, TalhaTalhaNisarBalster, TorstenTorstenBalsterHartwig, AndreasAndreasHartwigWagner, VeitVeitWagnerWark, MichaelMichaelWarkKortz, UlrichUlrichKortz2022-03-062022-03-062020https://publica.fraunhofer.de/handle/publica/26465110.1021/acs.inorgchem.0c00875We report on the synthesis and characterization of the first polyoxo-noble-metalate-containing metal-organic framework (MOF) material, wherein the preformed MIL-101 has been impregnated with the discrete, cuboid-shaped polyoxopalladate [Pd13Se8O32]6- (Pd13Se8), leading to the composite Pd13Se8@MIL-101. This material was characterized by FTIR, TGA, elemental analysis, powder-XRD, N2 sorption (BET), SEM-EDX, and XPS. Furthermore, the Pd13Se8@MIL-101 composite was shown to be an effective, stable, and recyclable heterogeneous precatalyst for the Suzuki-Miyaura cross-coupling reaction at room temperature utilizing environmentally benign solvents, such as water and methanol.enpalladiumcompositesmetal organic frameworksCatalystscatalysis620546660671journal article