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  4. Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes
 
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2018
Journal Article
Titel

Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

Abstract
In binary ionic liquid/Li salt mixtures with the novel asymmetric anion FTFSI, electrophoretic mobility mi values of all ion species were determined using electrophoretic NMR. Li was determined to migrate in negatively charged Li-anion clusters towards the anode. This vehicular transport mechanism was shown to have decreasing relevance at elevated salt concentrations.
Author(s)
Brinkkötter, Marc
Giffin, Guinevere A.
Fraunhofer-Institut für Silicatforschung ISC
Moretti, Arianna
Jeong, Sangsik
Passerini, Stefano
Schönhoff, Monika
Zeitschrift
Chemical communications
Thumbnail Image
DOI
10.1039/c8cc01416g
Language
English
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Fraunhofer-Institut für Silicatforschung ISC
Tags
  • Lithiumionenleiter

  • Elektrolyte

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