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  4. Thermal and corrosion properties of silicon nitride for copper die casting components
 
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2013
Journal Article
Title

Thermal and corrosion properties of silicon nitride for copper die casting components

Abstract
Due to the high melting temperature of copper and copper alloys, conventional die-steel components used in pressure die casting these materials exhibit short service lifetimes and undergo thermal fatigue. Thermal and corrosion properties of silicon nitride were studied to assess the material's applicability in substituting conventional die-steels in casting copper and copper alloys. In this study, experiments were conducted to test the thermal shock resistance and corrosion behaviour of a commercial silicon nitride in contact with molten pure copper. The results did not indicate any corrosive reaction between silicon nitride and pure copper. However, the presence of copper oxides at high temperatures accelerated the oxidation of the ceramic resulting in considerable loss of material. The thermal shock behaviour of silicon nitride proved to be adequate for the application.
Author(s)
Khader, I.
Renz, A.
Kailer, A.
Haas, D.
Journal
Journal of the European Ceramic Society  
Funder
Bundesministerium für Wirtschaft und Technolgie BMWi (Deutschland)  
Open Access
DOI
10.24406/publica-r-231910
10.1016/j.jeurceramsoc.2012.10.005
File(s)
N-236437.pdf (3.87 MB)
Language
English
Fraunhofer-Institut für Werkstoffmechanik IWM  
Keyword(s)
  • silicon nitride

  • copper casting

  • die casting

  • oxidation

  • corrosion

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