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  4. Catalytic membrane reactors for partial oxidation using perovskite hollow fiber membranes and for partial hydrogenation using a catalytic membrane contactor
 
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2007
Journal Article
Title

Catalytic membrane reactors for partial oxidation using perovskite hollow fiber membranes and for partial hydrogenation using a catalytic membrane contactor

Abstract
Two consecutive model reactions of the type A -> B -> C are studied in two kinds of catalytic membrane reactors. The partial oxidation of methane to synthesis gas due to CH4 + (1)/O-2(2) -> CO + 2H(2) was investigated in a novel type of permselective membrane reactor using perovskite hollow fibers for the selective separation of oxygen from air. Partial hydrogenations were studied in a pore-through-flow membrane reactor as a special type of a catalytic membrane contactor. The catalytically functionalized pores of the membrane provide a medium with defined contact times for the cofeed of hydrogen and an unsaturated hydrocarbon, and the attempts of the scale-up of the successful laboratory experiments to the pilot scale are reported.
Author(s)
Caro, J.
Caspary, K.J.
Hamel, C.
Hoting, B.
Kölsch, P.
Langanke, B.
Nassauer, K.
Schiestel, Thomas  orcid-logo
Schmidt, A.
Schomäcker, R.
Seidel-Morgenstern, A.
Tsotsas, E.
Voigt, I.
Wang, H.
Warsitz, R.
Werth, S.
Wolf, A.
Journal
Industrial and Engineering Chemistry Research  
DOI
10.1021/ie0609620
Language
English
Fraunhofer-Institut für Grenzflächen- und Bioverfahrenstechnik IGB  
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