Daboss, SvenSvenDabossKnittel, PeterPeterKnittelNebel, Christoph E.Christoph E.NebelKranz, ChristineChristineKranz2022-03-062022-03-062019https://publica.fraunhofer.de/handle/publica/25868810.1002/smll.2019020992-s2.0-85068506104Scanning probe microscopy techniques providing information on conductivity, chemical fluxes, and interfacial reactivity synchronized with topographical information have gained importance within the last decades. Herein, a novel colloidal atomic force microscopy (AFM) probe is presented using a spherical boron‐doped diamond (BDD) electrode attached and electrically connected to a modified silicon nitride cantilever. These conductive spherical BDD-AFM probes allow for electrochemical force spectroscopy. The physical robustness of these bifunctional probes, and the excellent electrochemical properties of BDD renders this concept a unique multifunctional tool for a wide variety of scanning probe studies including conductive AFM, hybrid atomic force-scanning electrochemical microscopy, and tip‐integrated chem/bio sensing.en667620journal article