Ailion, D.C.D.C.AilionGuenther, B.B.Guenther2022-03-022022-03-021985https://publica.fraunhofer.de/handle/publica/172854Application of the T1Drho pulse sequence often leads to a two-component relaxation decay due to nonadiabatic effects near the magic angle thetam which creates a serious danger of T1Drho misinterpretation. These effects were studied in detail for various fluorides and it was discovered that three different sources of nonadiabaticity may occur during T1Drho measurements.enBariumfluoridKernspinrelaxationKernspinresonanzNMRPulstechnikrelaxation620660671538Nonadiabatic effects on rotating-frame dipolar relaxation time measurements.Nichtadiabatische Effekte bei der Messung dipolarer Relaxationszeiten im rotierenden Systemjournal article