Arnold, MichaelMichaelArnoldKatzmann, JuliaJuliaKatzmannNaik, AakashAakashNaikGörne, Arno LudwigArno LudwigGörneHärtling, ThomasThomasHärtlingGeorge, JanineJanineGeorgeSchuster, ChristianeChristianeSchuster2022-10-172022-10-172022https://publica.fraunhofer.de/handle/publica/42768010.1039/D2TC01773C2-s2.0-85135100608A recent approach to measure electron radiation doses in the kGy range is the use of phosphors with an irradiation dose-dependent luminescence decay time. However, the applicability of the previously investigated material NaYF4:Yb3+,Er3+ is limited as it shows pronounced fading. Therefore, in this work, a modified SrF2 synthesis is presented that results in SrF2 nanoparticles codoped with Yb and either Er, Hm, or Tm. To assess their suitability as dosimeter material, dose response, as well as its degree of fading over 50 up to 140 days after irradiation were measured. Fading rates as small as 5% in SrF2:Er,Yb and 4% in SrF2:Ho,Yb were derived, which are comparable to established dosimeter materials. A combination of spectroscopy, diffraction and DFT calculations was used to elucidate the effect of irradiation, pointing towards the formation of a secondary phase of Yb2+ that we predict could be Yb2OF2. This irreversible formation of a secondary phase is considered to be the explanation for the low fading behavior in SrF2-based phosphors compared to NaYF4:Yb, Er, a highly attractive feature for electron beam dosimetry.enDosimetersElectron beamsFluorine compoundsIrradationPhosphorRare earthsSynthesis (chemical)Thulium compoundsYtterbium compoundsjournal article