Schoene, K.K.SchoeneBruckert, H.-J.H.-J.BruckertJürling, H.H.JürlingSteinhanses, J.J.Steinhanses2022-03-032022-03-031996https://publica.fraunhofer.de/handle/publica/18807310.1016/0021-9673(95)00751-2Two methods are presented for the derivatization of Adamsite (578-94-9): bromination to give 2,2',4,4',6,6'-hexabromodophenylamine (64524-09-0) - method A - and pyrolytic ethylation with dimethylformamide diethylacetal (1188-33-6) to give 10-ethyl-5,10-dihydrophenarsazine (53573-13-0) - method B. For the gas chromatographic analysis, atomic emission and mass spectrometric detection were applied. With regard to practicability and reliability, method B proved to be superior to method A.en10-chloro-5,10-dihydrophenarsazineAdamsitederivatizationgas chromatographyGCwarfare agents570610620660543journal article