Köntges, W.W.KöntgesPerkhun, P.P.PerkhunKammerer, J.J.KammererAlkarsifi, R.R.AlkarsifiWürfel, UliUliWürfelMargeat, O.O.MargeatVidelot-Ackermann, C.C.Videlot-AckermannSimon, J.-J.J.-J.SimonSchröder, Rasmus R.Rasmus R.SchröderAckermann, J.J.AckermannPfannmöller, M.M.Pfannmöller2022-03-062022-03-062020https://publica.fraunhofer.de/handle/publica/26226110.1039/c9ee03535dThe efficiency of organic solar cells with donor polymers and non-fullerene acceptors depends on a complex morphology. Similar chemical and electronic structures impede generating in-depth insights in morphological details. We visualise molecular arrangements and the nanomorphology in PBDB-T:ITIC blends by correlating transmission electron micrographs and material distribution maps. Material phases are identified by machine learning on hyperspectral data from electron spectroscopic imaging. We observe a specific polymorph of ITIC after thermal annealing. During annealing, enhanced by the presence of additives, PBDB-T acts as nucleation site for ITIC due to strong p-p-interactions of the electron withdrawing groups of both molecules. This leads to efficient charge transport paths in ITIC phases with direct p-p-contact to PBDB-T at the interface. We conclude that p-p-stacking between donor and acceptor molecules facilitates charge carrier generation within mixed interface regions.enPhotovoltaikNeuartige Photovoltaik-Technologienorganische Solarzelle621333697journal article