Sandfort, VincenzVincenzSandfortTrabold, Barbara M.Barbara M.TraboldAbdolvand, AmirAmirAbdolvandBolwien, CarstenCarstenBolwienRussell, Philip S.J.Philip S.J.RussellWöllenstein, JürgenJürgenWöllensteinPalzer, StefanStefanPalzer2022-03-052022-03-052017https://publica.fraunhofer.de/handle/publica/25108110.3390/s17122714The fast and reliable analysis of the natural gas composition requires the simultaneous quantification of numerous gaseous components. To this end, fiber-enhanced Raman spectroscopy is a powerful tool to detect most components in a single measurement using a single laser source. However, practical issues such as detection limit, gas exchange time and background Raman signals from the fiber material still pose obstacles to utilizing the scheme in real-world settings. This paper compares the performance of two types of hollow-core photonic crystal fiber (PCF), namely photonic bandgap PCF and kagomé-style PCF, and assesses their potential for online determination of the Wobbe index. In contrast to bandgap PCF, kagomé-PCF allows for reliable detection of Raman-scattered photons even below 1200 cm−1, which in turn enables fast and comprehensive assessment of the natural gas quality of arbitrary mixtures.enraman spectroscopyWobbe Indexphotonic crystal fiberKagoménatural gas621547journal article