Methods of the ecotoxicological evaluation of chemicals. Photochemical degradation in the gas phase. Vol. 6: OH reaction rate constants and tropospheric lifetimes of selected environmental chemicals

Becker, K.-H.K.-H.BeckerBiehl, H.M.H.M.BiehlBruckmann, P.P.BruckmannFink, E.H.E.H.FinkFühr, F.F.FührKlöpffer, W.W.KlöpfferZellner, R.R.ZellnerZetzsch, C.C.Zetzsch2022-03-072022-03-071984https://publica.fraunhofer.de/handle/publica/284560Techniques for the determination of rate constants for the reactions of OH radicals in the gas-phase and in solution are described. Rate constants are reported for 17 alkanes, 8 alkenes and alkynes, 15 oxygenated aliphatics, 5 chlorinated aliphatics, 26 aromatics, 4 nitrogen containing compounds, 7 sulfur containing compounds and 6 inorganic compounds. A method for the conversion of rate constants to tropospheric lifetimes is described. (ITA)enChemikalie(anorganisch)Chemikalie(organisch)GeschwindigkeitskonstanteHydroxylradikalMeßtechnik615610620Methods of the ecotoxicological evaluation of chemicals. Photochemical degradation in the gas phase. Vol. 6: OH reaction rate constants and tropospheric lifetimes of selected environmental chemicalsMethoden zur ökotoxikologischen Bewertung von Chemikalien. Photochemischer Abbau in der Gasphase. Band 6. Bericht 1980-1983book