Kim, Yong-ilYong-ilKimStepien, DominikDominikStepienMoon, HyeinHyeinMoonSchönherr, KayKaySchönherrSchumm, BenjaminBenjaminSchummKuenzel, MatthiasMatthiasKuenzelAlthues, HolgerHolgerAlthuesBresser, DominicDominicBresserPasserini, StefanoStefanoPasserini2023-05-122023-05-122023https://publica.fraunhofer.de/handle/publica/44193210.1021/acsami.3c007792-s2.0-85154070166To increase the energy density of today’s lithium batteries, it is necessary to develop an anode with higher energy density than graphite or carbon/silicon composites. Hence, research on metallic lithium has gained a steadily increasing momentum. However, the severe safety issues and poor Coulombic efficiency of this highly reactive metal hinder its practical application in lithium-metal batteries (LMBs). Herein, the development of an artificial interphase is reported to enhance the reversibility of the lithium stripping/plating process and suppress the parasitic reactions with the liquid organic carbonate-based electrolyte. This artificial interphase is spontaneously formed by an alloying reaction-based coating, forming a stable inorganic/organic hybrid interphase. The accordingly modified lithium-metal electrodes provide substantially improved cycle life to symmetric Li||Li cells and high-energy Li||LiNi0.8Co0.1Mn0.1O2 cells. For these LMBs, 7 μm thick lithium-metal electrodes have been employed while applying a current density of 1.0 mA cm-2, thus highlighting the great potential of this tailored interphase.enartificial interphaselithium metaltin chloridelithium nitratebatteryjournal article