Caldera-Cruz, E.E.Caldera-CruzZhang, K.K.ZhangTsuda, T.T.TsudaTkachov, RomanRomanTkachovBeryozkina, T.T.BeryozkinaKiriy, N.N.KiriyVoit, B.B.VoitKiriy, A.A.Kiriy2023-01-032023-01-032022https://publica.fraunhofer.de/handle/publica/43051210.1002/admi.2021013792-s2.0-85123841558A pair of hole-conducting polymers comprising 3,6-linked carbazole and meta-linked anisole derivatives having solubilizing moieties to enable their solution processability, and complementarily reactive side-groups (azide and alkyne) for cross-linking, are synthesized and characterized. The polymers can be cross-linked either by thermal annealing at relatively low temperatures in the 85-110 °C range, or by UV irradiation. A general applicability of the latter for a photolithographic patterning of the hole conducting polymer is proven. The polymers have an ionization potential (IP) of 5.8 eV, close to the IP of a small molecule hole-conductor tris(4-carbazoyl-9-ylphenyl)amine (TCTA). In combination with a strong dopant hexacyano-trimethylene-cyclopropane (CN6CP), but not with commercial 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ), the polymers can be efficiently p-doped to increase their conductivity by 5-6 orders of magnitude, as measured in devices with a lateral setup. Taken together, these characteristics suggest that the synthesized polymers are promising candidates for their use in solution-processable organic light-emitting diodes as hole-injection layer and hole-transporting layer materials, which will be verified in the upcoming work.enconductivitycross-linkingdopinghole-injection layershole-transporting layerssolution-processable semiconductorsjournal article