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Analysis of nitrophenols and other polar nitroaromatic compounds in ammunition wastewater by high-field proton nuclear magnetic resonance (1H-NMR) spectroscopy and chromatographic methods

 
: Preiß, A.; Lewin, U.; Wennrich, L.; Findeisen, M.; Efer, J.

Fresenius Journal of Analytical Chemistry 357 (1997), Nr.6, S.676-683
ISSN: 0937-0633
Englisch
Zeitschriftenaufsatz
Fraunhofer ITA ( ITEM) ()
ammunition; analytical chemistry; aromatic compound; chemistry; chromatographic analysis; environmental chemistry; explosives; gas chromatography; groundwater; high performance liquid chromatography; nitro compound; Nitroamines; nitrophenol; nuclear magnetic resonance spectroscopy; sewage; water; water chemistry

Abstract
It is shown that by using high-field proton nuclear magnetic resonance (1H-NMR) spectroscopy it is possible, without prior separation, to analyse nitrophenols and other acidic nitroaromatic compounds in the "ph 2 extract" of ammunition wastewater. The 1H-NMR chemical shifts data of a variety of reference compounds are presented. Two groundwater samples from the former ammunition plant in Elsnig (Saxony) were analysed by 1H-NMR and also by chromatographic methods (GC/MS, HPLC). The results are compared and discussed.

: http://publica.fraunhofer.de/dokumente/PX-3833.html