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Charge balancing and optical contrast optimization in Fe-MEPE/Ni1-xO electrochromic devices containing a Li reference electrode

 
: Niklaus, Lukas; Schott, Marco; Posset, Uwe; Mihelčič, Mohor; Jerman, Ivan; Giffin, Guinevere A.

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Solar energy materials and solar cells 227 (2021), Art. 111080, 8 S.
ISSN: 0927-0248
Englisch
Zeitschriftenaufsatz
Fraunhofer ISC ()
electrochromic device; metallopolymers; non-stoichiometric nickel oxide; reference electrode; charge balancing

Abstract
A three-electrode cell setup enables to evaluate the redox behavior of both electrodes, i.e., iron-based metallopolymers (Fe-MEPE) and a complementary switching non-stoichiometric nickel oxide (Ni1-xO, multilayer structure), in detail during full cell operation. In this work, electrochromic devices (ECDs) with a Li reference electrode and different charge density ratios between the electrode materials have been studied (spectro-)electrochemically. The charge density ratio between the electrodes affects the cell voltage, optical contrast, response time, and cycling stability. Here, a neutral-colored bright state was obtained for the unbalanced configuration (ECD-1, charge density ratio Fe-MEPE:Ni1-xO 2 = 2:1, underbalanced) and the balanced configuration (ECD-2, charge density ratio Fe-MEPE:Ni1-xO 3 = 1:1, balanced). The operating voltage range of the ECDs can be narrowed by using a balanced or overbalanced Ni1-xO electrode, e.g., 1.5 V ↔ -1 V for ECD-3 (charge density ratio Fe-MEPE:Ni1-xO 5 = 1:3, overbalanced). Moreover, the cycling stability is enhanced from just a few cycles (ECD-1) to over 1000 potentiostatic switching cycles (ECD-2 and ECD-3).

: http://publica.fraunhofer.de/dokumente/N-636237.html