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Unravelling the water adsorption in a robust iron carboxylate metal-organic framework

 
: Lenzen, D.; Eggebrecht, J.G.; Mileo, P.G.M.; Fröhlich, D.; Henninger, S.; Atzori, C.; Bonino, F.; Lieb, A.; Maurin, G.; Stock, N.

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Chemical communications 56 (2020), Nr.67, S.9628-9631
ISSN: 0022-4936
ISSN: 0009-241X
ISSN: 1359-7345
Englisch
Zeitschriftenaufsatz
Fraunhofer ISE ()
Thermische Systeme und Gebäudetechnik; adsorption; adsorption chiller; MOF; water management; energieeffizientes Gebäude; Lüftungs- und Klimatechnik; Thermische Speicher für Gebäude; Wärmepumpen

Abstract
A Fe-MOF was obtained from aqueous solution in high yield under reflux. The water sorption properties were studied by powder X-ray diffraction, volumetric and gravimetric sorption experiments and molecular simulations. The subsequent filling of hydrophobic and hydrophilic pores as well as the stability of the material are demonstrated.

: http://publica.fraunhofer.de/dokumente/N-615360.html