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Direct observation of lithium metal dendrites with ceramic solid electrolyte

 
: Golozar, Maryam; Paolella, Andrea; Demers, Hendrix; Savoie, Sylvio; Girard, Gabriel; Delaporte, Nicolas; Gauvin, Raynald; Guerfi, Abdelbast; Lorrmann, Henning; Zaghib, Karim

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Volltext ()

Scientific Reports 10 (2020), Art. 18410, 11 S.
ISSN: 2045-2322
Englisch
Zeitschriftenaufsatz, Elektronische Publikation
Fraunhofer ISC ()

Abstract
Dendrite formation, which could cause a battery short circuit, occurs in batteries that contain lithium metal anodes. In order to suppress dendrite growth, the use of electrolytes with a high shear modulus is suggested as an ionic conductive separator in batteries. One promising candidate for this application is Li7La3Zr2O12 (LLZO) because it has excellent mechanical properties and chemical stability. In this work, in situ scanning electron microscopy (SEM) technique was employed to monitor the interface behavior between lithium metal and LLZO electrolyte during cycling with pressure. Using the obtained SEM images, videos were created that show the inhomogeneous dissolution and deposition of lithium, which induce dendrite growth. The energy dispersive spectroscopy analyses of dendrites indicate the presence of Li, C, and O elements. Moreover, the cross-section mapping comparison of the LLZO shows the inhomogeneous distribution of La, Zr, and C after cycling that was caused by lithium loss near the Li electrode and possible side reactions. This work demonstrates the morphological and chemical evolution that occurs during cycling in a symmetrical Li–Li cell that contains LLZO. Although the superior mechanical properties of LLZO make it an excellent electrolyte candidate for batteries, the further improvement of the electrochemical stabilization of the garnet–lithium metal interface is suggested.

: http://publica.fraunhofer.de/dokumente/N-608548.html