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Hier finden Sie wissenschaftliche Publikationen aus den FraunhoferInstituten. Studying the bivariate tacticity distribution of poly1octene using twodimensional liquid chromatography coupled with NMR
 Polymer 174 (2019), S.7785 ISSN: 00323861 

 Englisch 
 Zeitschriftenaufsatz 
 Fraunhofer LBF () 
Abstract
The application properties of poly1olefins depend on their molar mass and the microstructure i.e., tacticity. While average values for the latter are available from NMR, its distribution along and across the molar mass axis is not yet accessible. Two samples of poly1octene with different average tacticity were chosen for the investigation with liquid chromatography and offline NMR detection. Because of the relatively low molar mass of the samples, liquid adsorption chromatography (LAC) is then a function of two parameters i.e., molar mass and tacticity. To study the tacticity distribution independent from the molar mass, samples were first preparatively fractionated by sizeexclusion chromatography (SEC). Analysis of the SEC fractions showed a gradient of tacticity along the molar mass axis. The isolated SEC fractions were then preparatively separated by LAC using porous graphite as stationary phase. NMR analysis of the LAC fractions then revealed a fractionation according to tacticity. Notably, two distinct populations that differ in tacticity were shown, which may be a result of different polymerization pathways. A comparison of the experimental results with theoretical calculations confirms that the configuration of the macromolecules in solution determines the retention on the stationary phase in LAC.