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Fundamental Mechanisms With Reactive Infiltration of Silicon Melt Into Carbon Capillaries

: Hofbauer, Peter J.; Rädlein, Edda; Raether, Friedrich


Advanced energy materials 21 (2019), Nr.8, Art. 1900184, 11 S.
ISSN: 1614-6840
ISSN: 1614-6832
Fraunhofer ISC ()
reaktive Infiltration; Kohlenstoffkapillare; Siliziumschmelze; C / SiC-Verbundwerkstoffe

The LSI process, that is, the infiltration of molten silicon into porous structures, is one of the most economical techniques for the production of dense C/SiC composites. However, despite decades of development, the phenomena at the infiltration front have not been understood sufficiently. Consequently, a comprehensive model of the reactive infiltration process, which would help to optimize the production process of C/SiC components, has not been established yet. A special thermo‐optical measuring furnace, TOM ac, enables in situ inspection during liquid silicon infiltration in a controlled atmosphere. Using a novel experimental set‐up, temperatures and atmospheres were varied during silicon melt infiltration into gap capillaries incorporated in glassy carbon. Results clearly demonstrate that the capillary effect is not the rate controlling process as commonly believed but show the importance of gas phase reactions. Besides optical inspection of the infiltration process, quenching experiments combined with SEM analyses of the samples provided a detailed insight into reaction mechanisms and transport processes.