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Sediment Challenge to Promising Ultra-low Fouling Hydrophilic Surfaces in the Marine Environment

: Koc, Julian; Simovich, Tomer; Schönemann, Eric; Chilkoti, Ashutosh; Gardner, Harrison; Swain, Geoffrey W.; Hunsucker, Kelli; Laschewsky, Andre; Rosenhahn, Axel


Biofouling 35 (2019), Nr.4, S.454-462
ISSN: 0892-7014
Deutsche Forschungsgemeinschaft DFG
DFG La 611/14-1
Neue zwitterionische Polymere für "low-fouling" Oberflächen
Deutsche Forschungsgemeinschaft DFG
DFG RO 2524/4-1
Neue zwitterionische Polymere für "low-fouling" Oberflächen
Fraunhofer IAP ()
hydrogel; polyzwitterion; field test; fouling release; marine biofouling; sediment

Hydrophilic coatings exhibit ultra-low fouling properties in numerous laboratory experiments. In stark contrast, the antifouling effect of such coatings in vitro failed when performing field tests in the marine environment. The fouling release performance of nonionic and zwitterionic hydrophilic polymers was substantially reduced compared to the controlled laboratory environment. Microscopy and spectroscopy revealed that a large proportion of the accumulated material in field tests contains inorganic compounds and diatomaceous soil. Diatoms adhered to the accumulated material on the coating, but not to the pristine polymer. Simulating field tests in the laboratory using sediment samples collected from the test sites showed that incorporated sand and diatomaceous earth impairs the fouling r elease characteristics of the coatings. When exposed to marine sediment from multiple locations, particulate matter accumulated on these coatings and served as attachment points for diatom adhesion and enhanced fouling. Future developments of hydrophilic coatings should consider accumulated sediment and its potential impact on the antifouling performance.