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Investigation of electrochemical processes in CO2 sensitive electrodes

: Dietrich, Stefan; Kusnezoff, Mihails; Mosch, Sindy; Baumgärtner, Christoph

Volltext ()

Proceedings. MDPI AG 2 (2018), Nr.13, Art. 903, 5 S.
ISSN: 2504-3900
Eurosensors Conference <32, 2018, Graz>
Bundesministerium fur Wirtschaft und Energie BMWi (Deutschland)
IGF-ZIM; 150576
Zeitschriftenaufsatz, Konferenzbeitrag, Elektronische Publikation
Fraunhofer IKTS ()
CO2-Sensor; impedance spectroscopy; electrode process

The electrode processes governing response behavior of a solid electrolyte CO2 sensor have been studied using electrochemical impedance spectroscopy on symmetric cells exposed to various temperatures and gas compositions. It was shown that the electrochemical processes leading to potential formation at the Au/Na2CO3 electrode can be described by adapting models commonly used in the field of molten carbonate fuel cells.