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Thermo-catalytic reforming of co-form® rejects (waste cleansing wipes)

: Ouadi, Miloud; Greenhalf, Charles; Jäger, Nils; Speranza, Lais Galileu; Hornung, Andreas


Journal of analytical and applied pyrolysis 132 (2018), S.33-39
ISSN: 0165-2370
Fraunhofer UMSICHT Sulzbach-Rosenberg ()
organic waste; thermal conversion; energy vector; pyrolysis; synthesis gas

Co-form® products are typically used for personal hygiene care (cleansing wipes), household cleaning (pads and mops) and absorbent applications. Co-form® is a thermo-bonded multilayer nonwoven composite and Kimberly-Clark patented its process in 2008. Co-form® rejects are composed of 30% plastic polypropylene and 70% woodpulp fibre. It is difficult to recycle and to-date no research articles explore pyrolytic valorisation for its energyrecovery. This paper investigated pyrolytic valorisation of co-form® rejects into energy vectors. Pelletised coform® rejects obtained from a secondary fibre paper mill were processed using a laboratory scale 2 kg/h Thermo-Catalytic Reforming (TCR®) reactor. The TCR® process combines intermediate pyrolysis, using an auger reactor to heat the material under moderate temperatures (350–450 °C) and moderate solid residence times (minutes) inthe complete absence of Oxygen, with post catalytic reforming in a fixed bed reactor at 700 °C. Pelletised coform® rejects were successfully converted into 12 wt% bio-oil, 9 wt% aqueous phase liquid, 8 wt% char and 71 wt% syngas products. The bio-oil higher heating value was found to be 39.36 MJ/kg, comparable to biodiesel. Naphthalene was found to be the most abundant aromatic compound within the oil, with a relative abundance of15.22% measured by GC–MS. Oleic acid methyl ester (15.86%) was the most abundant long chain hydrocarbon detected. The higher heating value of produced gas was 11.02 MJ Nm3 and char 30.79 MJ/kg. TCR® conversion of co-form® rejects proved to be a feasible route for the valorisation of this waste stream into sustainable energy vectors. In previous works, gasification processes could not successfully convert organic waste streams with a high plastic content, without implications attributed to agglomeration and melting of plastics. The TCR® process overcome these issues with no evidence of agglomeration or melting of plastics present within the reactor. The success was believed to be through applying moderate heating rates (°C/min) and temperatures (max 700 °C), aswell as the mechanical effect of continuous mixing of material within the reactor via the internal auger screw. Overall, TCR® is a promising future route for the valorisation of co-form® rejects to produce energy vectors.