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A fast and easy perovskite solar cell simulation tool featuring ion migration

: Fell, Andreas; Walter, Daniel; Glunz, Stefan W.

Volltext urn:nbn:de:0011-n-4774496 (382 KByte PDF)
MD5 Fingerprint: c9f617663263ee5e037154a0bb72d4b0
Erstellt am: 13.1.2018

Smets, A.:
33rd European Photovoltaic Solar Energy Conference and Exhibition, EU PVSEC 2017 : Proceedings of the international conference held in Amsterdam, The Netherlands, 25 September - 29 September 2017
München: WIP, 2017
ISBN: 978-3-936338-47-8
ISBN: 3-936338-47-7
European Photovoltaic Solar Energy Conference and Exhibition (EU PVSEC) <33, 2017, Amsterdam>
European Commission EC
H2020; 655852; Quokka Maturation
A mature Quokka for everyone – advancing the capabilities and accessibility of numerical solar cell simulations
Konferenzbeitrag, Elektronische Publikation
Fraunhofer ISE ()
Solarzellen - Entwicklung und Charakterisierung; Photovoltaik; Neuartige Photovoltaik-Technologien; Farbstoff- und Perowskitsolarzellen; modeling; perovskite; Quokka; simulation; ion

Extensions for perovskite solar cells (PSCs) within the solar cell simulation tool Quokka3 are presented, accounting for ion migration. In the “1D detailed solver” the fully coupled equations describing semiconductor carrier transport, ion transport (anions and cations) as well as the general Shockley-Read-Hall formalism (trapping) are implemented, both as steady-state and transient mode. Numerical challenges arising from the narrowness of the Debye layer and the large difference in times scales between semiconductor and ion transport are successfully addressed. Example simulations are presented, showing the influence of pre-bias voltage on fast JV-sweeps, as well as an interaction between ion redistribution and surface recombination that replicates transient open-circuit voltage responses in a MAPbI3 PSC.