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The Chemistry of Metal-Organic Frameworks: Synthesis, Characterization, and Applications

: Kaskel, Stefan


Weinheim: Wiley-VCH, 2016, 833 S. (2 Vols)
ISBN: 978-3-527-33874-0
ISBN: 978-3-527-69305-4
ISBN: 978-3-527-69308-5
Fraunhofer IWS ()

Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry.Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application.A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.


VOLUME 1 /// 1 Introduction / 2 Network Topology // PART I: MOF CHEMISTRY OF METALLIC CLUSTERS AND OTHER NODES / 3 Reticular Chemistry of Metal-Organic Frameworks Composed of Copper and Zinc Metal Oxide Secondary Building Units as Nodes / 4 Alkaline Earth Metal-Based Metal-Organic Frameworks: Synthesis, Properties, and Applications / 5 Synthesis, Structure, and Selected Properties of Aluminum-, Gallium-, and Indium-Based Metal-Organic Frameworks / 6 Group 4 Metals as Secondary Building Units: Ti, Zr, and Hf-based MOFs / 7 Iron and Groups V- and VI-based MOFs / 8 Platinum Group Metal-Organic Frameworks / 9 Group 3 Elements and Lanthanide Metals // PART II: FUNCTIONAL LINKERS / 10 Extended Linkers for Ultrahigh Surface Area Metal-Organic / 11 Porous Metal Azolate Frameworks / 12 Functional Linkers for Catalysis / 13 Chiral Linker Systems / 14 Functional Linkers for Electron-Conducting MOFs / 15 Linkers with Optical Functionality /// VOLUME 2 // PART III: SPECIAL MOF CLASSES AND MORPHOLOGY DESIGN OF MOFS / 16 Nanoparticles / 17 SURMOFs: Liquid-Phase Epitaxy of Metal-Organic Frameworks on Surfaces / 18 Granulation and Shaping of Metal-Organic Frameworks // PART IV PROGRESS IN ADVANCED CHARACTERIZATION OF MOFS / 19 Adsorption Methodology / 20 Nuclear Magnetic Resonance of Metal-Organic Frameworks / 21 Electron Paramagnetic Resonance / 22 IR and Raman Spectroscopies Probing MOFs Structure, Defectivity, and Reactivity / 23 In Situ X-ray Diffraction and XAS Methods / 24 In Situ Studies of the Crystallization of Metal-Organic Frameworks / 25 Role of Molecular Simulations in the Field of MOFs / 26 Defects and Disorder in MOFs / Appendix A: MOF Suppliers / Appendix B: Datasheet