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Photochromic composite for random lasing based on porous polypropylene infiltrated with azobenzene-containing liquid crystalline mixture

 
: Lisinetskii, V.; Ryabchun, A.; Bobrovsky, A.; Schrader, S.

:

ACS applied materials & interfaces 7 (2015), Nr.48, S.26595-26602
ISSN: 1944-8244
ISSN: 0013-936X
ISSN: 1944-8252
Bundesministerium für Bildung und Forschung BMBF
03FH086PX2
Englisch
Zeitschriftenaufsatz
Fraunhofer IAP ()

Abstract
We report on a new low-cost and easily fabricated type of liquid crystalline polymer composites demonstrating low threshold random lasing, which can be used as a cheap and simple mirror-less laser source. The composite is based on mass-producible commercially available porous polypropylene (Celgard 2500) infiltrated with low-molar-mass liquid crystal material doped with Rhodamine 800 laser dye. Excitation with red nanosecond laser (630 nm) induces random lasing with the emission peak in NIR spectral range (804 nm) with noticeable degree of linear polarization. The possibility to control the lasing threshold and polarization of the output light with UV radiation through photoswitching of liquid crystal phase from nematic to isotropic is demonstrated. The photocontrollable phase switching is achieved by reversible E/Z isomerization of the azobenzene dopant introduced to the nematic host matrix. It is revealed that the isotropic state of liquid crystal provides more efficient random lasing with lower threshold due to significant scattering of the ordinary wave.

: http://publica.fraunhofer.de/dokumente/N-382266.html