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High temperature infrared absorption of CVD diamond measured by laser calorimetry

Laserkalorimetrische Messung der Hochtemperatur-Infrarotabsorption in CVD-Diamant
 
: Wörner, E.; Wild, C.; Müller-Sebert, W.; Grimm, M.; Koidl, P.

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Diamond and Related Materials 14 (2005), Nr.3-7, S.580-583
ISSN: 0925-9635
European Conference on Diamond, Diamond-Like Materials, Carbon Nanotubes, Nitrides and Silicon Carbide <15, 2004, Trentino>
Englisch
Zeitschriftenaufsatz, Konferenzbeitrag
Fraunhofer IAF ()
defect; Defekt; optical property; optische Eigenschaft; infrared absorption; Infrarotabsorption; CVD-Diamond; CVD-Diamant

Abstract
The infrared absorption of CVD diamond at a wavelength of 10.6 mu m was measured as a function of temperature between 20 and 500 deg C. CVD diamond of different structural quality was investigated. Optical spectroscopy and infrared Raman scattering were used for the structural characterization. Laser calorimetry was applied to measure the IR absorption at elevated temperatures. For these measurements, CVD diamond devices with integrated heater and temperature sensor were prepared. The optical absorption at a given temperature was determined by comparing the temperature rise induced by CO2 laser irradiation with the equivalent electrically induced temperature rise. Samples with a room temperature absorption coefficient of alpha=0.096 cm-1 and alpha=0.85 cm-1 were investigated. Despite this large difference, the absolute increase of the absorption coefficient with increasing temperature was found to be similar for the two samples. It increased by a value of about 0.5 cm-1 between 0 and 500 deg C.

: http://publica.fraunhofer.de/dokumente/N-31433.html