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Graphene nanoplatelets supported metal nanoparticles for electrochemical oxidation of hydrazine

 
: Wan, Q.J.; Liu, Y.; Wang, Z.H.; Wei, W.; Li, B.B.; Zou, J.; Yang, N.

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Electrochemistry communications 29 (2013), S.29-32
ISSN: 1388-2481
Englisch
Zeitschriftenaufsatz
Fraunhofer IAF ()
graphene nanoplatelets (GNPs); metal nanoparticles; electrochemical oxidation of hydrazine; electrodeposition

Abstract
Graphene nanoplatelets have been applied as the support to electrodeposit monometallic Au and Pd nanoparticles as well as bimetallic Au-Pd nanoparticles. These nanoparticles have been characterized with scanning electron microscope, energy dispersive X-ray spectroscopy, X-ray diffraction spectroscopy, and electrochemical techniques. They are further utilized as the catalysts for electrochemical oxidation of hydrazine. The oxidation peak potential is -0.35 and 0.53 V (vs. SCE) when monometallic Pd and Au nanoparticle are used as the catalysts. When bimetallic nanoparticles are applied as the catalyst, their composition affects the peak potential and peak current for the oxidation of hydrazine. Higher oxidation current is achieved when bimetallic Au-Pd nanoparticles with an atomic ratio of 3:1 are deposited on graphene nanoplatelets. Metal nanoparticle-loaded graphene nanoplatelets are thus novel platforms for electrocatalytic, electroanalytical, environmental, and related applications.

: http://publica.fraunhofer.de/dokumente/N-241852.html