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Hydrogen desorption properties of melt-spun and hydrogenated Mg-based alloys using in situ synchrotron X-ray diffraction and TGA

 
: Kalinichenka, S.; Röntzsch, L.; Baehtz, C.; Weißgärber, T.; Kieback, B.

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Journal of alloys and compounds 509 (2011), Nr.SUPPL. 2, S.S629-S632
ISSN: 0925-8388
Englisch
Zeitschriftenaufsatz
Fraunhofer IFAM, Institutsteil Pulvermetallurgie und Verbundwerkstoffe Dresden ()

Abstract
Three magnesium-based alloys, Mg90Ni10, Mg 80Ni10Y10 and Mg85Cu 5Ni5Y5, were prepared by melt-spinning and compared regarding their hydrogen desorption properties. Their hydrogen desorption kinetics after activation and hydrogenation was investigated by thermogravimetry at different temperatures in the range from 150 °C to 250 °C. It was found that Mg80Ni10Y10 exhibits a much faster desorption kinetics in comparison to Mg90Ni 10 and Mg85Cu5Ni5Y5 of up to 1.3 wt.%-H2/min. The corresponding crystal phase transformations were investigated in detail by in situ synchrotron X-ray diffraction. It was found that the kinetics of hydrogenation is controlled by different reaction pathways for Mg90Ni10, Mg80Ni 10Y10 and Mg85Cu5Ni 5Y5.

: http://publica.fraunhofer.de/dokumente/N-189352.html