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Toughening of epoxy resins modified with polyetherester block copolymers. The influence of modifier molecular architecture on mechanical properties

: Höfflin, F.; Könczöl, L.; Döll, W.; Morawiec, J.; Mülhaupt, R.


Journal of applied polymer science 76 (2000), Nr.5, S.623-634 : Ill., Lit.
ISSN: 0021-8995
ISSN: 1097-4628
Fraunhofer IWM ()
epoxy resin; mechanical properties; morphology; Polyetherester; segmented block copolymers; thermoplastic elastomer; toughening

Thermoplastic elastomers based on polyetheresters with polyoxytetramethylene soft segments and poly(hexamethyleneterephthalate) hard segments were used to toughen anhydride-cured epoxy resins. The ratio between hard and soft segments and the crystallinity of the hard segments prepared by incorporating poly(hexamethyleneisophthalate) in the block copolymer were varied in order to examine the effect of the modifier's molecular architecture on morphology and mechanical properties of the resin, such as toughness, strength, and stiffness. The experimental data show that segmented polyetheresters are suitable toughening agents for epoxies. The compatibility between resin and toughener and also the mechanical properties of the modified resin depend on the ratio between the hard and soft segments. Epoxy resins blended with 10 wt per cent of the polyetherester exhibit an increase in toughness by 50-150%, while strength and modulus decrease by 20 per cent or less. An optimal phase adhesion at levels between 70 and 85 wt per cent of soft segments in the modifier results in a maximum of toughness enhancement (by about 150 per cent) of the resin accompanied with only a slight drop in strength and stiffness (by about 15 per cent). The glass transition temperature is only slightly affected.