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Uptake kinetics of nitrosyl chloride on aqueous solutions

: Behnke, W.; Frenzel, A.; George, C.; Scheer, V.; Zetzsch, C.

	Mirabel, P. ; European Commission, Directorate-General for Science, Research and Development: Homogeneous and heterogeneous chemical processes in the troposphere : Strasbourg, 25 and 26 September 1995 Luxembourg: Office for Official Publications of the European Communities, 1996 (Air pollution research report 57) ISBN: 92-827-6147-9 pp.18-23
	Joint EC/EUROTRAC Workshop LACTOZ/HALIPP <1995>

	English
	Conference Paper
	Fraunhofer ITA ( ITEM) ()
	air pollution; atmospheric chemistry; cloud; global warming; ozone; phosgene; photochemical degradation; photochemistry; physical chemistry; sea spray; theoretical chemistry; troposphere

Abstract
We measured the reactive uptake of NOCl on water and on solutions of NaCl, HCl and NaOH with a wetted-wall flowtube technique. The observed uptake coefficient is close to the upper detection limit of the technique. A reversible reaction kinetics was not observed. The hydrolysis on water and on NaCl and HCl solution leads to the release of gas-phase HONO.

: http://publica.fraunhofer.de/documents/PX-37972.html