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1991
Journal Article
Titel
Formation of atomic Cl from sea spray via photolysis of nitryl chloride - determination of the sticking coefficient of N2O5 on NaCl aerosol
Abstract
The sticking coefficient of NsO5 on NaCl aerosol is determined in a smog chamber at 292 K, and the rate constant for the consecutive chemical reaction leading to formation of ClNO2 is determined at various relative humidities between 71 and 92 per cent. A preliminary evaluation of these first experiments indicates that the sticking coefficient increases with increasing humidity from 0.024 to 0.05 in that range, whereas the portion leading to ClNO2 decreases from 0.61 to 0.3.
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