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Field emission of nitrogenated amorphous carbon films

 
: Hoffmann, U.; Weber, A.; Klages, C.-P.; Matthee, T.

:

Carbon 37 (1999), No.5, pp.753-757
ISSN: 0008-6223
English
Journal Article
Fraunhofer IST ()
a-C:N; activation; amorphous carbon; discharge; electron field emission; FED; Feldemission

Abstract
Field emitter films based on nitrogenated amorphous carbon (a-C:N) were deposited on different chromium patterns on glass by sputtering of graphite employing an electron cyclotron resonance plasma as argon and nitrogen ion source. The a-C:N films contain between 0.6 and 21 at % nitrogen. All films have a low resistivity (<0.1 Omega cm) and a microhardness of about 15 GPa indicating a high content of sp(2) bonds. The vacuum electronic properties of the films were checked in an UHV chamber in a plane to plane set-up. To localize the emission sites the excitation of a low voltage phosphor (ZnO:Zn) was monitored by a CCD camera. After an activation by vacuum are discharges emission of electrons occurred at macroscopic electrical fields au low as 3.2 V/mu m. The discharges generate delaminated a-C:N film fragments that bear the FE current due to field enhancement. Discharge and therefore FE only took place at the edges of the emitter stripes due to a macroscopic field enhancement. Two kind of activation were found leading to different microstructures of the emitter and different FE characteristics. The influence of substrate bias, nitrogen content, film thickness and emitter geometry on the field emission was also surveyed.

: http://publica.fraunhofer.de/documents/PX-14391.html