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68.9% Efficient GaAs-Based Photonic Power Conversion Enabled by Photon Recycling and Optical Resonance

: Helmers, H.; Lopez, E.; Höhn, O.; Lackner, D.; Schön, J.; Schauerte, M.; Schachtner, M.; Dimroth, F.; Bett, A.W.

Fulltext urn:nbn:de:0011-n-6373273 (807 KByte PDF)
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Created on: 24.8.2021

Physica status solidi. Rapid research letters 15 (2021), No.7, Art. 2100113, 7 pp.
ISSN: 1862-6254
ISSN: 1862-6270
Journal Article, Electronic Publication
Fraunhofer ISE ()
Photovoltaik; back reflector; Optical Power Transmission; photonic power; photonic power converter; photon recycling; resonance; III-V- und Konzentrator-Photovoltaik; III-V Epitaxie und Solarzellen; Power-by-Light

For solar cells operating under the broad-band solar spectrum, the photovoltaic conversion efficiency is fundamentally limited by transmission and thermalization losses. For monochromatic light, these losses can be minimized by matching the photon energy and the absorber material's bandgap energy. Furthermore, for high-crystal-quality direct semiconductors, radiative recombination dominates the minority carrier recombination. Light-trapping schemes can leverage reabsorption of thereby internally generated photons. Such photon recycling increases the effective excess carrier concentration, which, in turn, increases photovoltage and consequently conversion efficiency. Herein, a back surface reflector underneath a GaAs/AlGaAs rear-heterojunction structure leverages photon recycling to effectively reduce radiative recombination losses and therefore boost the photovoltage. At the same time, resonance in the created optical cavity is tailored to enhance near-bandgap absorption and, thus, minimize thermalization loss. With a thin film process and a combined dielectric–metal reflector, an unprecedented photovoltaic conversion efficiency of 68.9 ± 2.8% under 858 nm monochromatic light at an irradiance of 11.4 W cm−2 is demonstrated.