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Modeling and Multi-Criteria Optimization of a Process for H2O2 Electrosynthesis

: Kurnatowski, M. von; Bortz, M.

Fulltext ()

Processes 9 (2021), No.2, Art. 399, 24 pp.
ISSN: 2227-9717 (electronic)
Journal Article, Electronic Publication
Fraunhofer ITWM ()

This article introduces a novel laboratory-scale process for the electrochemical synthesis of hydrogen peroxide (H2O2). The process aims at an energy-efficient, decentralized production, and a mathematical optimization of it is presented. A dynamic, zero-dimensional mathematical model of the reactor is set up in Aspen custom modeler®. The proposed model constitutes a reasonable compromise between complexity and convergence. After thoroughly determining the reaction kinetics by adjustment to experimental data, the reactor unit is embedded in an Aspen Plus® flowsheet in order to investigate its interaction with other unit operations. The downstream contains another custom module for membrane distillation. Electricity appears as a resource in the process, and optimization shows that it reaches product purities of up to 3 wt.-%. Both the process optimization and the adjustment of the reaction kinetics are treated as multi-criteria optimization (MCO) problems.