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  4. Effective screening of medium-assisted van der Waals interactions between embedded particles
 
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2021
Journal Article
Title

Effective screening of medium-assisted van der Waals interactions between embedded particles

Abstract
The effect of an implicit medium on dispersive interactions of particle pairs is discussed, and simple expressions for the correction relative to vacuum are derived. We show that a single point Gauss quadrature leads to the intuitive result that the vacuum van der Waals C6-coefficient is screened by the permittivity squared of the environment evaluated near to the resonance frequencies of the interacting particles. This approximation should be particularly relevant if the medium is transparent at these frequencies. In this manuscript, we provide simple models and sets of parameters for commonly used solvents, atoms, and small molecules.
Author(s)
Fiedler, J.
nstitute of Physics, University of Freiburg; Department of Physics and Technology, University of Bergen,
Walter, M.
Fraunhofer-Institut für Werkstoffmechanik IWM  
Buhmann, S.Y.
Institute of Physics, University of Kassel
Journal
The Journal of chemical physics  
Funder
Deutsche Forschungsgemeinschaft DFG  
Deutsche Forschungsgemeinschaft DFG  
Deutsche Forschungsgemeinschaft DFG  
Open Access
Link
Link
DOI
10.1063/5.0037629
Additional full text version
Landing Page
Language
English
Fraunhofer-Institut für Werkstoffmechanik IWM  
Keyword(s)
  • dispersive interactions

  • embedded particles

  • Gauss quadratures

  • interacting particles

  • resonance frequency

  • simple expression

  • small molecules

  • Van Der Waals interactions

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