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2019
Journal Article
Titel
Iron(III) v-diketonates: CVD precursors for iron oxide film formation
Abstract
Complexes [Fe(v-diketonate)3] (v-diketonate = 2-acetylcyclopentanoate (3a), = 2-acetylcyclohexanoate (3b), = 4,4-dimethyl-1-phenyl pentanedionate (3c)) were synthesized by the reaction of FeCl3 with the respective v-diketones in presence of NaOH. The molecular structures of 3a and 3c in the solid state are discussed, confirming an octahedral coordination sphere at Fe(III) setup by the three bidentate-bonded v-diketonato ligands. Variation of the v-diketonato ligands allowed to influence the thermal behavior and vapor pressure of the complexes. TG-MS ( = Thermo Gravimetry-Mass Spectrometry) studies, exemplarily carried out on 3a, confirmed the release of the v-diketonate ligands. Complexes 3a-c were applied as MOCVD (=Metal-Organic Chemical Vapor Deposition) precursors for the deposition of Fe2O3 thin films on silicon substrates. It was found that with 3a,b, conformal and dense carbon-free g- and a-Fe2O3 layers were produced at 450 °C, which was verified by scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray photon spectroscopy.
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