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Selection and optimization of a suitable pretreatment method for miscanthus and poplar raw material

 
: Seibert-Ludwig, Daniel; Hahn, Thomas; Hirth, Thomas; Zibek, Susanne

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Global change biology. Bioenergy. Online journal 11 (2019), No.1, pp.171-180
https://onlinelibrary.wiley.com/journal/17571707
ISSN: 1757-1693
ISSN: 1757-1707
English
Journal Article, Electronic Publication
Fraunhofer IGB ()
design of experiment; miscanthus; modified severity factor; organosolv; poplar; pretreatment

Abstract
Miscanthus and poplar are very promising second-generation feedstocks due to the high growth rates and low nutrient demand. The aim of the study was to develop a systematic approach for choosing suitable pretreatment methods evaluated with the modified severity factor (log R"0). Optimal pretreatment results in a high delignification grade, low cellulose solubilization and increased accessibility for enzymatic hydrolysis while revealing minimal log R"0 values. In order to do so, several reaction approaches were compared. Acid-catalyzed organosolv processing carried out for miscanthus and poplar revealed the highest delignification grade leading to a relatively high glucose yield after enzymatic saccharification. In both cases, a design of experiments approach was used to study the influence of relevant parameters. Modeling the data resulted in the identification of optimum pretreatment conditions for miscanthus with concentrations of 0.16% H2SO4 and 50% EtOH at 185°C for a retention time of 60 min. Experimental validation of these conditions revealed an even higher delignification degree (88%) and glucose yield (85%) than predicted. 0.19% H2SO4 and 50% EtOH were determined as optimum concentrations, 182°C and 48 min identified as optimum pretreatment conditions for poplar; the delignification degree was 84% and the resulting glucose yield 70%.

: http://publica.fraunhofer.de/documents/N-540871.html