Fraunhofer-Gesellschaft

Publica

Hier finden Sie wissenschaftliche Publikationen aus den Fraunhofer-Instituten.

Femtosecond laser-induced transformations in ultra-low expansion glass

Microstructure and local density variations by vibrational spectroscopy
 
: Efthimiopoulos, I.; Palles, D.; Richter, S.; Hoppe, U.; Möncke, D.; Wondraczek, L.; Nolte, S.; Kamitsos, E.I.

:

Journal of applied physics 123 (2018), No.23, Art.233105, 17 pp.
ISSN: 0021-8979
ISSN: 1089-7550
English
Journal Article
Fraunhofer IOF ()

Abstract
We report X-ray diffraction, resonance Raman, and infrared (IR) results on pristine ultra-low expansion (ULE) glass, a binary titanosilicate glass with 5.67 mol. % TiO2. ULE processing by femtosecond (fs) laser radiation leads to nanograting writing and photo-darkening for imaging and data storage. We investigate here the vibrational/structural changes induced by fs laser irradiation of ULE at 515 nm. Optical imaging revealed the formation of micro-cavities, and Raman mapping showed molecular oxygen trapped in such cavities of laser-irradiated ULE glass. While titanium in the pristine glass was found predominantly in tetrahedral Ti4+ sites highly dispersed in the silicate matrix, Raman and IR reflectance spectroscopy on laser-irradiated ULE indicated the formation of Ti3+ sites; Ti3+ octahedral sites are formed in the shells of cavities and aggregate in amorphous Ti2O3-type clusters, while the glass around and below cavities contains Ti3+ tetrahedral sites dispersed in the silicate network. Laser-processed ULE glass was found to also exhibit local restructuring of the silicate matrix. Shifts of the strong IR band at about 1080–1100 cm−1 were translated into changes of the average Si-O-Si bond angle in the laser-transformed areas and found to reflect local density variations; the average local density increases relative to silica glass up to about 8% in the shells of micro-cavities and decreases by about 0.5% in the surrounding material. Chemical processes were proposed to account for photo-darkening and the local structural transformation effect in the probed areas of the fs laser-processed ULE glasses.

: http://publica.fraunhofer.de/documents/N-524564.html