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Interaction with spectral consequences between TM+ type cations located in oxide glass hosts

: Goldstein, Adrian; Vulfson, Marina; Shames, Alex; Katz, Michael; Räthel, Jan


European journal of glass science and technology. B, Physics and chemistry of glasses 58 (2017), No.6, pp.243-248
ISSN: 1753-3570
ISSN: 1750-6689
ISSN: 0031-9090
ISSN: 1753-3562
Journal Article
Fraunhofer IKTS ()

Interaction between different transition element cations (TM+), simultaneously present in a glass host, affects the electromagnetic radiation absorption spectrum profile. The effects may be quite drastic in certain cases. In this research an attempt was made to determine whether interaction occurs when certain TM(1) and TM(2) low concentration dopants are simultaneously present in a glass host. Any structural factors that control such processes were also investigated. It was found that an interplay between the host-basicity and the electronic structure of TM(1,2) determines this process. Only redox type interaction was detected. Dopants pairs like Cr+Cu and Cr+Mn interacted in a suitable silicate host, and Ti+Mn in one based on P2O5. Interaction is quite a rare event.