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Positive effect of the fluorine moiety on the oxygen storage capacity of UiO-66 metal-organic frameworks

 
: Piscopo, C.G.; Trapani, F.; Polyzoidis, A.; Schwarzer, M.; Pace, A.; Loebbecke, S.

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New journal of chemistry 40 (2016), No.10, pp.8220-8224
ISSN: 0398-9836
ISSN: 1144-0546
English
Journal Article
Fraunhofer ICT ()

Abstract
Two series of fluorine-containing UiO-66 have been synthesized, replacing the 1,4-benzodicarboxylic acid linker with increasing amounts of 2-fluoro-1,4-benzodicarboxylic acid or 2-trifluoromethyl-1,4-benzodicarboxylic acid. The capacity to store oxygen and nitrogen within these MOFs has been tested, which revealed a positive correlation between the fluorine content and the oxygen storage performances.

: http://publica.fraunhofer.de/documents/N-422051.html