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A novel dichromic self-referencing optical probe SrO:Bi(3+),Eu(3+) for temperature spatially and temporally imaging

: Fu, Jipeng; Pang, Ran; Jiang, Lihong; Jia, Yonglei; Sun, Wenzhi; Zhang, Su; Li, Chengyu


Dalton transactions 45 (2016), No.34, pp.13317-13323
ISSN: 1477-9226
ISSN: 2209-2386
ISSN: 1477-9234
Journal Article
Fraunhofer IKTS ()

A novel dichromic luminescence probe SrO:Eu3+,Bi3+ for temperature sensing is achieved. The detailed luminescence properties, e.g., the excitation emission spectra, energy transfer efficiency, luminescence decay lifetimes and temperature dependent luminescence are comprehensively studied. The two dominant emissions 5D0 → 7F2 transition of Eu3+ and the 3P1 → 1S0 transition of Bi3+ display adjustable spectrum area. The interaction effect between Eu3+ and Bi3+ are proposed. The dichromic emissions are specifically responding to temperature with high sensitivity at ultra-wide range from 30 to 400 °C. Spatial and temporal temperature images on an aircraft surface have been successfully realized under excitation of commercial 365 nm light emitting diode (LED) by painting the SrO:Bi3+,Eu3+ phosphor on a plane model. Finally, the thermal quenching mechanism revealed by Arrhenius theory is employed to interpret the temperature sensitive luminescence behaviour.