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Inkjet printed organic light-emitting electrochemical cells for disposable lab-on-chip applications manufactured at ambient atmosphere

 
: Shu, Z.; Pabst, O.; Beckert, E.; Eberhardt, R.; Tünnermann, A.

:

Materials today. Proceedings 3 (2016), No.3, pp.733-738
ISSN: 2214-7853
International Conference on Nanosciences & Nanotechnologies (NN) <12, 2015, Thessaloniki>
International Symposium on Flexible Organic Electronics (ISFOE) <8, 2015, Thessaloniki>
International Summer Schools on Nanosciences & Nanotechnologies - Organic Electronics & Nanomedicine (ISSON) <9, 2015, Thessaloniki>
English
Journal Article, Conference Paper
Fraunhofer IOF ()

Abstract
Microfluidic lab-on-a-chip devices can be used for chemical and biological analyses such as DNA tests or environmental monitoring. Such devices integrate most of the basic functionalities needed for the analysis on a microfluidic chip. When using such devices, cost and space intensive lab equipment is thus not necessary. However, in order to make a monolithic and costefficient/ disposable sensing device, direct integration of excitation light source for fluorescent sensing is often required. Organic light emitting diodes (OLEDs) have the advantages of self-emitting property, high luminous efficiency, full-color capability, wide viewing angle, high contrast, low power consumption, low weight and flexibility. All these capacitate OLEDs to be a suitable optical source for microfluidic devices. However, low work function cathode and/or electron injection layer like Ba, LiF are indispensable for high bright OLEDs, which require vacuum deposition and inert fabrication atmosphere. Hereby we introduce a fully solution processable deviation of OLEDs, organic light-emitting electrochemical cells (OLECs) as a low-cost excitation light source for a microfluidic sensing platform. By mixing metal ions and a solid electrolyte with light-emitting polymers as active materials, an in-situ doping and in-situ PN-junction can be generated within a three layer sandwich device. Because of this doping effect, work function adaption is not necessary and air-stable cathodes like silver can be used. A manufacturing process for fully solution-processed OLECs is presented, which consist of an inkjet-printed silver cathode, spin-coated blue light-emitting polymer plus dopants and an inkjet-printed PEDOT:PSS transparent top anode. Furthermore, by replacing silver with ITO, a fully transparent blue OLEC is able to emit > 2500 cd/m(2) light under pulsed driving mode, which fulfils requirements for simple fluorescent on-chip sensing applications.

: http://publica.fraunhofer.de/documents/N-404562.html